a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\left(2\right)\\ 2Al+2NaOH+2H_2O\rightarrow2NaAlO_2+3H_2\)

Cho hỗn hợp tác dụng với NaOH, chất rắn không tan là Fe

=> m_Fe= 1,12 (g) \(\Rightarrow n_{Fe}=0,02\left(mol\right)\)

Ta có: \(n_{H_2\left(2\right)}=n_{Fe}=0,02\left(mol\right)\)

=> \(n_{H_2\left(1\right)}=\Sigma n_{H_2}-n_{H_2\left(2\right)}=0,065-0,02=0,045\left(mol\right)\)

\(\Rightarrow n_{Al}=\dfrac{2}{3}n_{H_2\left(1\right)}=0,03\left(mol\right)\)

\(\Rightarrow m_{Al}=0,03.27=0,81\left(g\right)\)

\(\Rightarrow\%m_{Al}=41,97\%,\%m_{Fe}=58,03\%\)

b) \(m_{FeCl_2}=0,02.127=2,54\left(g\right)\\ m_{AlCl_3}=0,03.133,5=4,005\left(g\right)\)

Gọi : \(\left\{{}\begin{matrix}n_{Al_2O_3}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\)⇒ 102a + 65b = 2,505(1)

\(Al_2O_3 + 6HCl \to 2AlCl_3 + 3H_2O\\ Zn + 2HCl \to ZnCl_2 + H_2\)

Muối gồm : \(\left\{{}\begin{matrix}AlCl_3:2a\left(mol\right)\\ZnCl_2:b\left(mol\right)\end{matrix}\right.\)⇒ 133,5.2a + 136b = 6,045(2)

Từ (1)(2) suy ra : a = 0,015 ; b = 0,015

Vậy :

\(\%m_{Al_2O_3} = \dfrac{0,015.102}{2,505}.100\% = 61,08\%\\ \%m_{Zn} = 100\% - 61,08\% = 38,92\%\)

Theo PTHH : \(n_{HCl} = 6a + 2b = 0,12(mol)\\ \Rightarrow C\%_{HCl} = \dfrac{0,12.36,5}{200}.100\% = 2,19\%\)

Zn+2HCl→ZnCl2+H2

 2Al+6HCl→2AlCl3+3H2

Gọi số mol HCllà x

n H2=\(\dfrac{1}{2}\)n HCl=0,5x

Bảo toàn khối lượng: mkl+mHCl=mmuối+mH2

6,05+36,5x=13,15+0,5x.2

→x=0,2 mol

mHCl=0,2.36,5=7,3 gam

=>m =mddHCl=\(\dfrac{7,3}{10\%}\)=73gam

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,Zn+2HCl\to ZnCl_2+H_2\\ b,n_{ZnCl_2}=0,1(mol)\\ \Rightarrow m_{ZnCl_2}=0,1.136=13,6(g)\\ c,n_{Zn}=0,1(mol)\\ \Rightarrow \%_{Zn}=\dfrac{0,1.65}{20}.100\%=32,5\%\\ \Rightarrow \%_{Ag}=100\%-32,5\%=67,5\%\)

áp dụng công thức là ra

Câu 1:

Gọi : nMg=a(mol); nMgO=b(mol) (a,b>0)

a) PTHH: Mg + 2 HCl -> MgCl2 + H2

a________2a_______a______a(mol)

MgO +2 HCl -> MgCl2 + H2O

b_____2b_______b___b(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}24a+40b=8,8\\22,4a=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)

=> mMg=0,2.24=4,8(g)

=>%mMg= (4,8/8,8).100=54,545%

=> %mMgO= 45,455%

b) m(muối)=mMg2+ + mCl- = 0,3. 24 + 0,6.35,5=28,5(g)

c) V=VddHCl=(2a+2b)/2=0,3(l)=300(ml)

Câu 2:

Ta có: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{HCl}=0,4\cdot2=0,8\left(mol\right)\end{matrix}\right.\)

PTHH: \(Ca+2HCl\rightarrow CaCl_2+H_2\uparrow\)

               0,2____0,4_____0,2____0,2   (mol)

           \(CaO+2HCl\rightarrow CaCl_2+H_2O\)

                0,2____0,4______0,2____0,2  (mol)

Ta có: \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{0,2\cdot40}{0,2\cdot40+0,2\cdot56}\cdot100\%\approx41,67\%\\\%m_{CaO}=58,33\%\\m_{CaCl_2}=\left(0,2+0,2\right)\cdot111=44,4\left(g\right)\end{matrix}\right.\)

PTHH: \(K_2O+2HCl\rightarrow2KCl+H_2O\)

            \(K_2SO_3+2HCl\rightarrow2KCl+SO_2\uparrow+H_2O\)

a) Ta có: \(\left\{{}\begin{matrix}n_{HCl}=\dfrac{200\cdot14,6\%}{36,5}=0,8\left(mol\right)\\n_{SO_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_3}=0,3\left(mol\right)\\n_{K_2O}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{K_2O}=\dfrac{0,1\cdot94}{0,1\cdot94+0,3\cdot158}\cdot100\%\approx16,55\%\\\%m_{K_2SO_3}=83,45\%\end{matrix}\right.\)

b) Theo các PTHH: \(n_{KCl}=0,8\left(mol\right)\) \(\Rightarrow m_{KCl}=74,5\cdot0,8=59,6\left(g\right)\)

Mặt khác: \(\left\{{}\begin{matrix}m_{hh}=56,8\left(g\right)\\m_{SO_2}=0,3\cdot64=19,2\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{SO_2}=237,6\left(g\right)\)

\(\Rightarrow C\%_{KCl}=\dfrac{59,6}{237,6}\cdot100\%\approx25,1\%\)